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The uptake, translocation, and human bioaccessibility of metals originating from atmospheric fine particulate matters (PM) after foliar exposure is not well understood. Lettuce (Lactuca sativa L.) plants were exposed to micronic PbO, CuO, and CdO particulate matters (PMs) by the foliar pathway and mature plants (6 weeks old) were analyzed in terms of: (1) metal accumulation and localization on plant leaf surface, and metal translocation factor (TF) and global enrichment factor (GEF) in the plants; (2) shoot growth, plant dry weight (DW), net photosynthesis (Pn), stomatal conductance (Gs), and fatty acid ratio; (3) metal bioaccessibility in the plants and soil; and (4) the hazard quotient (HQ) associated with consumption of contaminated plants. Substantial levels of metals were observed in the directly exposed edible leaves and newly formed leaves of lettuce, highlighting both the possible metal transfers throughout the plant and the potential for human exposure after plant ingestion. No significant changes were observed in plant biomass after exposure to PbO, CuO, and CdO-PMs. The Gs and fatty acid ratio were increased in leaves after metal exposure. A dilution effect after foliar uptake was suggested which could alleviate metal phytotoxicity to some degree. However, plant shoot growth and Pn were inhibited when the plants are exposed to PbO, and necrosis enriched with Cd was observed on the leaf surface. Gastric bioaccessibility of plant leaves is ranked: Cd?>?Cu?>?Pb. Our results highlight a serious health risk of PbO, CuO, and CdO-PMs associated with consumption of vegetables exposed to these metals, even in newly formed leaves in the case of PbO and CdO exposure. Finally, the study highlights the fate and toxicity of metal rich-PMs, especially in the highly populated urban areas which are increasingly cultivated to promote local food.
相似文献Methods: This study seeks to develop a generalized evaluation scheme that can be used not only to assess the effectiveness of IMA on improving traffic safety at intersections but to facilitate comparisons across similar studies. The proposed evaluation scheme utilizes the concepts of traffic conflict in terms of time-to-collision (TTC) as a crash surrogate. This approach avoids the issue of having insufficient crash frequency data for system evaluation. To measure the effectiveness of IMA on reducing traffic conflicts, a relative risk is calculated for comparing the risk of with/without using the IMA. As a proof-of-concept study, this study applied the proposed evaluation scheme and reported the effectiveness of IMA on improving traffic safety in a field operation test (FOT). Seven test scenarios were conducted at 4 intersections, and a total of 40 participants were recruited to use the IMA for 6 months.
Results: It was estimated that IMA users have 26% fewer conflicts with TTC less than 5 s and have 15% fewer conflicts with TTC less than 4 s. However, the results vary across different sites and different definitions of conflicts in terms of TTC.
Conclusions: Overall, IMA is promising to effectively reduce angle crashes related to sight obstruction and has potential to reduce not only crash frequency but crash severity. 相似文献
For many clustered populations, the prior information on an initial stratification exists but the exact pattern of the population concentration may not be predicted. Under this situation, the stratified adaptive cluster sampling (SACS) may provide more efficient estimates than the other conventional sampling designs for the estimation of rare and clustered population parameters. For practical interest, we propose a generalized ratio estimator with the single auxiliary variable under the SACS design. The expressions of approximate bias and mean squared error (MSE) for the proposed estimator are derived. Numerical studies are carried out to compare the performances of the proposed generalized estimator over the usual mean and combined ratio estimators under the conventional stratified random sampling (StRS) using a real population of redwood trees in California and generating an artificial population by the Poisson cluster process. Simulation results show that the proposed class of estimators may provide more efficient results than the other estimators considered in this article for the estimation of highly clumped population.
相似文献China launched the One Belt & One Road (OBOR) initiative to minimize the energy resource shortage. The China’s nearby countries are rich in energy resources especially Middle East and North Africa (MENA) and Asian countries which make them ideal locations to cooperate with China in terms of energy resources, as 42.8% of world energy consumption belongs to OBOR countries. The present study elaborates the spatial distribution pattern of energy consumption disparities and its impact on environment. To do this, an entropy approach is utilized to compute the energy consumption inequalities in OBOR and its regions. The spatial and Pareto analysis show that MENA, East, and Southeast Asian economies have the highest degree of energy consumption inequalities, while European and Central Asian economies show the lowest energy consumption inequalities in OBOR region. The long-run estimates indicate that energy consumption inequalities enhance the CO2 emission in OBOR and its region except South and Southeast Asia. Financial development also has a significantly positive impact on CO2 emission in all models for OBOR and its regions except East Asia. Based on findings, the spatial distribution analysis is applicable to maintain balance in regional energy consumption inequality within OBOR and its regions.
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